菲涅耳体初至层析静校正技术的研究与应用

菲涅耳体初至层析静校正技术通过菲涅耳体初至层析反演方法建立复杂近地表速度模型,再利用该模型计算近地表一致性静校正量,然后应用计算的静校正量对地震剖面进行静校正处理,以提高成像质量.该技术主要包括初至拾取;初至层析反演近地表速度模型;模型底界面、基准面、替换速度等参数的确定;激发点和接收点静校正量的计算;静校正量的应用等...     

列车对列车无线通信中的信道特性分析

列车对列车(Train-to-train,T2T)通信能为现有车-地专网通信提供保障,其信道特性直接影响上层通信技术的应用.首先,根据铁路运营场景的空间分布结构和菲涅尔带理论提出一种适用于平原和长直隧道场景下追踪列车间直接通信的频率分配方案,并结合由降雨引起电波衰减的估算方法分析多频段无线信道的大尺度衰落.其次,推导T2T通信的最大多普勒频移计算公式,并通过射线跟踪法描述隧道内多径波,以分析小尺度衰落.最后,在同等速度条件下,仿真分析得出T2T通信低频段最大多普勒频移值明显低于车-地通信频移值.     

A flow cell for transient voltammetry and in situ grazing incidence X-ray diffraction characterization of electrocrystallized cadmium(II) tetracyanoquinodimethane

An easy to fabricate and versatile cell that can be used with a variety of electrochemical techniques, also meeting the stringent requirement for undertaking cyclic voltammetry under transient conditions in in situ electrocrystallization studies and total external reflection X-ray analysis, has been developed. Application is demonstrated through an in situ synchrotron radiation-grazing incidence X-ray diffraction (SR-GIXRD) characterization of electrocrystallized cadmium (II)-tetracyanoquinodimethane material, Cd(TCNQ)₂, from acetonitrile (0.1 mol dm⁻³ [NBu₄][PF₆]). Importantly, this versatile cell design makes SR-GIXRD suitable for almost any combination of total external reflection X-ray analysis (e.g., GIXRF and GIXRD) and electrochemical perturbation, also allowing its application in acidic, basic, aqueous, non-aqueous, low and high flow pressure conditions. Nevertheless, the cell design separates the functions of transient voltammetry and SR-GIXRD measurements, viz., voltammetry is performed at high flow rates with a substantially distended window to minimize the IR (Ohmic) drop of the electrolyte, while SR-GIXRD is undertaken using stop-flow conditions with a very thin layer of electrolyte to minimize X-ray absorption and scattering by the solution.     

同杆双回输电线路的固有频率测距算法

提出一种基于行波固有频率的同杆双回线路单端故障测距方法.针对不同的故障类型,通过推导故障点反射系数矩阵,判断模混杂情况,选择恰当的模量,对其进行频谱估计,并提取固有频率主成分.利用故障距离、固有频率和边界条件三者的数学关系求取测距结果.考虑到双回线路不能忽略分布电容对测距结果的影响和该测距算法的特点,采用对频率敏感的频...     

傅里叶变换红外光谱法测定白酒中乙醇含量

建立快速测定酒精饮品中乙醇含量的衰减全反射-傅里叶变换红外光谱（ATR-FTIR）法,以ZnSe槽行板为ATR晶体,以水为背景采集样品的FTIR图。以1 044 cm-1的C-OH伸缩振动为特征峰,用峰面积表示整个吸光度以消除尖峰干扰,建立了其线性关系数0.998 6,乙醇水溶液的检测限为0.2%。该方法准确、方便、快速,适用于酒精饮品中乙醇含量的快速测定。     

用电磁波速诊断XLPE电缆绝缘

XLPE电缆绝缘诊断的研究对于掌握电缆的绝缘老化状态,保证电力传输系统的安全可靠运行有着十分重要的意义。针对工程实际中大规模应用的诊断方法不多见的现状,提出了一种XLPE电缆状态检测的新方法,即用电磁波在一段XLPE电缆中的传播速度作为诊断这段电缆是否发生老化的依据。在阐明了该方法的原理和理论依据后介绍了所搭建的实验平...     

Evolution of structural and optical properties in the course of thermal evolution of sol-gel derived cobalt-doped gahnite

Thermal evolution of sol-gel derived gahnite (ZnAl₂O₄) with 4, 8 and 12 at.% of Zn replaced with Co was studied by thermal analysis techniques (DTA/TGA), X-ray diffraction (XRD) and UV-vis diffuse reflectance spectroscopy (DRS). Zinc-cobalt spinel powders were produced by gel heat treatment at temperatures as low as 400 °C. Crystal structure was characterized using Rietveld refinement of X-ray diffraction patterns for the samples annealed at 800 °C, simultaneously with the analysis of diffraction line broadening. It was found out that the distribution of Co²⁺ ions in tetrahedral and octahedral sites of zinc cobalt aluminate crystal lattice, crystallite size and lattice strain depend on Co loading. The green color of samples thermally treated at T < 800 °C has been explained as a consequence of partial oxidation of Co²⁺ ions at lower temperatures and accommodation of Co³⁺ ions in octahedral sites. Thermal treatment at higher temperatures promote gradual change of color from green to blue, characteristic for tetrahedrally coordinated Co²⁺ ions. The spectra evolution could be interpreted as a progressive reduction of Co³⁺ to Co²⁺ ions at higher temperatures.     

紫外激光双波段高反射镜的研制

通过非线性光学频率变换的方式,1 064 nm YAG激光可获得355 nm、266 nm波长的激光。在此系统中工作的反射镜必须同时满足两个波段的高反射。根据薄膜设计理论选择合适的镀膜材料,采用电子束离子辅助沉积工艺,经过参数优化和反复试验,在石英基片上制备了355 nm反射率为97.9%,266 nm反射率为96.8%的双波段反射镜,且在紫外波段355 nm的激光损伤阈值为1.76J/cm2,266 nm为1.12 J/cm2。测试结果表明,此反射镜的各项性能满足使用要求。     

CPML在3维HIFFDTD算法中的实现

文中将CPML引入3维弱无条件稳定算法HIE-FDTD中,详细推到了CPML在3维弱无条件稳定HIE-FDTD中的差分公式.为了验证CPML在3维HIE-FDTD中的吸波性能,建立了数值计算模型,并将CPML的吸波性能同其它几种常用的吸收边界条件进行了比较.结果显示,当将CPML层数设置为8时,其最大反射误差为-72 dB,远低于传统FDTD方法的反射误差.另外,当匹配层参数设置为α=0.05,可以在一个较大范围内选取κmax和σmax来实现最佳误差,从而使得在选值时易于预测反射情况.     

二维TE波中的HIE-CPML算法

文中将坐标伸缩完全匹配层CPML引入到弱无条件稳定算法HIE-FDTD中研究其吸波性能。详细推导了2维TE波模型中CPML在HIE-FDTD算法中应用的差分公式。为检验本文所提方法的吸波效能,建立了计算模型,将其与其它吸收边界条件的吸波性能进行了综合比较,计算了HIE-FDTD算法选取不同条件数时的反射误差,并详细说明如何合理选取α,κmax和σmax来实现最佳相对误差。结果显示：当将本文所提方法的CPML层数设置为8时,其反射误差为-62 dB,低于传统FDTD方法的-58 dB;当选取α=0.05,κmax=10,σmax/σopt=1.3可以实现低至-83 dB的最大相对误差;在仿真中,其比传统FDTD方法也约减少48%的计算时间。